M A T E R I A L S A F E T Y D A T A S H E E T
Modified Bitumen Adhesive Brush Grade Page: 1
PRODUCT NAME: Modified Bitumen Adhesive Brush Grade HMIS CODES: H F R P
PRODUCT CODE: #66 AF Brush
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: KARNAK CORPORATION
ADDRESS : 330 CENTRAL AVE.
CLARK, N.J. 07066
EMERGENCY PHONE : (800)424-9300 DATE PRINTED : 08/20/97
INFORMATION PHONE : (732)388-0300 NAME OF PREPARER : N/A
========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
------------------------------------------------------------------------------------
PETROLEUM HYDROCARBONS 64742-95-6 2.7 68 10-20
OSHA PEL: 100 PPM,
ACGIH TLV: 100 PPM
ATTAPULGITE CLAY 12174-11-7 N/A N/A 5-15
OSHA PEL: N/A,
ACGIH TLV: 5 MG/M3, OTHER: N/A
* 1,2,4-TRIMETHYLBENZENE 95-63-6 2.7 68 5
OSHA TWA: 25 PPM,
ACGIH TWA: 25 PPM
STYRENE-BUTADIENE BLOCK COPOLYMER 9003-55-8 N/A N/A 2-7
OSHA PEL: N/A,
ACGIH TLV: N/A, OTHER: N/A
* XYLENE 1330-20-7 6.6 68 2
OSHA TWA: 100 PPM, OSHA STEL: 150 PPM
ACGIH TWA: 100 PPM, ACGIH STEL: 150 PPM
CELLULOSE FIBERS 9004-34-6 N/A N/A .5-3
OSHA PEL: 5 MG/M3,
ACGIH TLV: 5 MG/M3, OTHER: N/A
* CUMENE 98-82-8 2.7 68 1
OSHA TWA: 50 PPM (SKIN),
ACGIH TWA: 50 PPM (SKIN)
ACTIVE CATIONIC SALT 28701-67-9 .1 68 < 1
OSHA PEL: N/A,
ACGIH TLV: N/A, OTHER: N/A
POLYALICYCLIC RESIN 69430-35-9 N/A N/A < 1
OSHA PEL: N/A,
ACGIH TLV: N/A, OTHER: N/A
ETHYLBENZENE 100-41-4 2.7 68 < 1
OSHA TWA: 100 PPM, OSHA STEL: 125 PPM
ACGIH TWA: 100 PPM, ACGIH STEL: 125 PPM
* Indicates toxic chemical(s) subject to the reporting requirements of section 313
of Title III and of 40 CFR 372.
=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============
BOILING RANGE: 315 F SPECIFIC GRAVITY (H2O=1): 0.99
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
SOLUBILITY IN WATER: NEGLIGIBLE.
APPEARANCE AND ODOR: BLACK PASTE, MILD SOLVENT ODOR.
================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============
FLASH POINT: 107 F METHOD USED: PMCC
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1 UPPER: 6
EXTINGUISHING MEDIA: FOAM, CO2, DRY CHEMICAL, WATER FOG
SPECIAL FIREFIGHTING PROCEDURES
POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND STRUCTUAL
FIREFIGHTERS PROTECTIVE CLOTHING WILL PROVIDE LIMITED PROTECTION.
UNUSUAL FIRE AND EXPLOSION HAZARDS
FLAMMABLE/COMBUSTIBLE MATERIAL; MAY BE IGNITED BY HEAT, SPARKS OR FLAMES.
VAPORS MAY TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY EXPLODE IN HEAT OF FIRE. VAPOR EXPLOSION HAZARD INDOORS,
OUTDOORS OR IN SEWERS. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
M A T E R I A L S A F E T Y D A T A S H E E T
Modified Bitumen Adhesive Brush Grade Page: 2
EXPLOSION HAZARD.
======================== SECTION V - REACTIVITY DATA =======================
STABILITY: STABLE
CONDITIONS TO AVOID
EXTREME HEAT, OPEN FLAME.
INCOMPATIBILITY (MATERIALS TO AVOID)
ISOLATE FROM OXIDIZERS, HEAT AND OPEN FLAME.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS
FIRE MAY PRODUCE IRRITATING OR POISONOUS GASES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
==================== SECTION VI - HEALTH HAZARD DATA =======================
INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL OR RESPIRATORY IRRITATION, DIZZINESS,
FATIGUE, NAUSEA, HEADACHE, AND POSSIBLE UNCONSCIOUSNESS.
SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE
CAN CAUSE SEVERE IRRITATION, REDNESS, TEARING, BLURRED VISION.
SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
SKIN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS.
INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA.
HEALTH HAZARDS (ACUTE AND CHRONIC)
ACUTE - HEADACHE, DIZZINESS, NAUSEA, IRRITATION. CHRONIC - LOSS OF APPETITE, NOSE BLEEDS.
CARCINOGENICITY: NTP CARCINOGEN: No IARC MONOGRAPHS: No OSHA REGULATED: No
N/A
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
PRE-EXISTING EYE, SKIN, OR RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
EMERGENCY AND FIRST AID PROCEDURES
MOVE VICTIM TO FRESH AIR AND CALL EMERGENCY MEDICAL CARE; IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION; IF BREATHING IS DIFFICULT, GIVE OXYGEN. IN CASE OF CONTACT
WITH MATERIAL, IMMEDIATELY FLUSH EYES WITH RUNNING WATER FOR AT LEAST 15 MINUTES.
WASH SKIN WITH SOAP AND WATER. REMOVE AND ISOLATE CONTAMINATED CLOTHING AN SHOES
AT THE SITE.
=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
SMALL LEAKS: TAKE UP WITH SAND OR OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO
CONTAINERS FOR LATER DISPOSAL. LARGE LEAKS:
DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL. STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
WASTE DISPOSAL METHOD
INCINERATE UNDER SAFE CONDITIONS OR DISPOSE OF IN ACCORDANCE WITH LOCAL STATE AND
FEDERAL REGULATIONS.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
DO NOT BREATHE VAPORS, USE WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY.
DON'T GET IN EYES. WEAR IMPERVIOUS CLOTHING. KEEP AWAY FROM HEAT AND FLAME.
OTHER PRECAUTIONS
SHUT OFF IGNITION SOURCES; NO FLAMES, SMOKING OR FLAMES IN HAZARD AREA.
===================== SECTION VIII - CONTROL MEASURES ======================
M A T E R I A L S A F E T Y D A T A S H E E T
Modified Bitumen Adhesive Brush Grade Page: 3
RESPIRATORY PROTECTION
WEAR RESPIRATOR IN CONFINED AREA.
VENTILATION
LOCAL EXHAUST RECOMMENDED.
PROTECTIVE GLOVES
NORMAL WORK GLOVES.
EYE PROTECTION
SAFETY GLASSES OR GOGGLES.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT
EYE BATH AND SAFETY SHOWER.
WORK/HYGIENIC PRACTICES
WASH HANDS BEFORE EATING OR USING RESTROOM. SMOKE ONLY IN APPROVED AREAS.
========================= SECTION IX - DISCLAIMER ==========================
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER,
NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING TO THE ACCURACY OF THIS DATA OR THE
RESULTS TO BE OBTAINED FROM THE USE THEREOF. KARNAK ASSUMES NO RESPONSIBILITY FOR
PERSONAL INJURY OR PROPERTY DAMAGE TO VENDEES, USERS OR THIRD PARTIES CAUSED BY
THE MATERIAL.
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