M A T E R I A L S A F E T Y D A T A S H E E T
PITCH ROOF COATING Page: 1
PRODUCT NAME: PITCH ROOF COATING
PRODUCT CODE: #168 AF
================== SECTION I - MANUFACTURER IDENTIFICATION =================
MANUFACTURER'S NAME: KARNAK CORPORATION
ADDRESS : 330 CENTRAL AVE.
CLARK, N.J. 07066
EMERGENCY PHONE : (800)424-9300 DATE PRINTED : 08/20/97
INFORMATION PHONE : (732)388-0300 NAME OF PREPARER : N/A
========== SECTION II - COMPOSITION/ WORKPLACE EXPOSURE LIMITS =============
CAS Reg. Appr. OSHA-PEL ACGIH TLV
Component Number Pct. TWA Ceiling TWA STEL
---------------------------------------------------------------------------------------
1. Coal tar pitch, 65996-93-2 50 0.2 mg/m3* NE 0.2 mg/m3* NE
high temp.
Including:
Acenaphthene 83-32-9 NE NE NE NE
Acenaphthylene 208-96-8 NE NE NE NE
Anthracene 120-12-7 NE NE 0.2 mg/m3* NE
Benzo[a]anthracene 56-55-3 NE NE A2 NE
Benzo[a]pyrene 50-32-8 0.2 mg/m3* NE A2 NE
Benzo[b]fluoranthene 205-99-2 NE NE A2 NE
Benzo[ghi]perylene 191-24-2 NE NE NE NE
Benzo[k]fluoranthene 207-08-9 NE NE NE NE
Carbazole 86-74-8 NE NE NE NE
Chrysene 218-01-9 0.2 mg/m3* NE A2 NE
Dibenz[a,h]anthracene 53-70-3 NE NE NE NE
Dibenzofuran 132-64-9 NE NE NE NE
Fluoranthene 206-44-0 NE NE NE NE
Fluorene 86-73-7 NE NE NE NE
Indene 95-13-6 NE NE 10 ppm NE
lndeno[1,2,3-cd]pyrene 193-39-5 NE NE NE NE
1-Methylnaphthalene 90-12-0 NE NE NE NE
2-Methylnaphthalene 91-57-6 NE NE NE NE
Naphthalene 91-20-3 10 ppm NE 10 ppm 15 ppm
Phenanthrene 85-01-8 0.2 mg/m3* NE 0.2 mg/m3* NE
Pyrene 129-00-0 0.2 mg/m3* NE 0.2 mg/m3* NE
2. Heavy petroleum dist. 64742-04-7 17 5 mg/m3 NE 5 mg/m3 10 mg/m3
3. Petroleum dist., 64741-59-9 25 5 mg/m3 NE 5 mg/m3 10 rng/m3
C9-C30
4. Allapulgite clay 8031-18-3 3 5 mg/m3** NE 10 mg/m3TD NE
5. Cellulose 9004-34-6 3 5 mg/m3** NE 10 mg/m3TD NE
6. Limestone 1317-65-3 2 5 mg/m3** NE 10 mg/m3TD NE
NOTES ON EXPOSURE LIMITS: NE = NOT ESTABLISHED.
TD = TOTAL DUST RF = RESPIRABLE FRACTION
*FOR COAL-TAR PITCH VOLATILES, BENZENE-SOLUBLE FRACTION
**RF. PEL-TWA FOR TD = 15 PPM.
========================== SECTION III - HEALTH HAZARDS ================================
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) CLASSIFICATION:
HEALTH: 2* FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: DEPENDS UPON CONDITIONS.
INHALATION:
HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE NOSE AND THROAT. OVEREXPOSURE CAN CAUSE HEADACHE, DIZZINESS, DROWSINESS, AND UNCONSCIOUSNESS. NOTE: THERE IS NO FORESEEABLE RISK OF WORKERS¼ INHALING SOLID CONSTITUENTS OF THIS MIXTURE.
EYE EXPOSURE:
M A T E R I A L S A F E T Y D A T A S H E E T
PITCH ROOF COATING PAGE: 2
VAPOR CAN IRRITATE EYES. LIQUID CONTACT CAN CAUSE REDNESS, TEARING, AND IRRITATION.
SOLIDS MAY SCRATCH EYEBALL. REPEATED OR PROLONGED EXPOSURE MAY CAUSE EYE DAMAGE.
HOT MATERIAL CAN BURN EYE TISSUE, POSSIBLY RESULTING IN LOSS OF EYESIGHT.
SKIN EXPOSURE:
LIQUID AND VAPORS CAN CAUSE SKIN IRRITATION AND DERMATITIS, INCLUDING ACNE. COAL TAR PITCH
IS A PHOTOTOXIC SUBSTANCE THAT, IN THE PRESENCE OF ULTRAVIOLET LIGHT (SUNLIGHT), CAN CAUSE A
SKIN REACTION SIMILAR TO AN EXAGGERATED SUNBURN, FREQUENTLY CAUSING BLISTERS. EXISTING SKIN
DISORDERS (E.G., ECZEMA OR SKIN ALLERGY) MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL. HOT
MATERIAL CAN CAUSE SEVERE HEAT BURNS.
INGESTION:
SWALLOWING CAN CAUSE SEVERE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, AND DEPRESSION
OF THE CENTRAL NERVOUS SYSTEM. SOLVENT CAN ENTER THE LUNGS DURING SWALLOWING OR VOMITING,
CAUSING LUNG INFLAMMATION AND DAMAGE.
DELAYED EFFECTS:
LONG-TERM OVEREXPOSURE TO COAL TAR PITCH CAN AFFECT SKIN PIGMENTATION. IT CAN CAUSE GROWTHS
ON THE SKIN OR SKIN CANCER. IT MAY CAUSE CANCER OF THE LUNGS, KIDNEYS, OR BLADDER.
CARCINOGENICITY DETERMINATIONS:
COAL TAR PITCH HAS BEEN DETERMINED BY IARC TO BE A HUMAN CARCINOGEN. COAL TAR PITCH AND
SEVERAL OF ITS SPECIFIC INGREDIENTS, INCLUDING BENZO[A]PYRENE, HAVE BEEN DETERMINED BY NTP
TO CAUSE CANCER IN EXPERIMENTAL ANIMALS.
======================== SECTION V - FIRST AID MEASURES =======================
INHALATION:
REMOVE SUBJECT TO FRESH AIR IMMEDIATELY. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS
STOPPED. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT. CONSULT A PHYSICIAN IF SYMPTOMS PERSIST.
EYE CONTACT:
FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN AT ONCE IF HOT
MATERIAL HAS CONTACTED EYE. OTHERWISE, SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN CONTACT:
IF CONTACTED BY UNHEATED MATERIAL OR LIGHT SPRAY, REMOVE CONTAMINATED CLOTHING, INCLUDING SHOES.
THEN REMOVE MATERIAL FROM SKIN WITH VEGETABLE OIL AND WASH THOROUGHLY WITH SOAP AND WATER.
HYDROCORTISONE CREAM MAY BE USED FOR RELIEF OF SKIN IRRITATION. CONSULT A PHYSICIAN IF
IRRITATION PERSISTS.
IF CONTACTED BY HOT LIQUID, DO NOT REMOVE CLOTHING IN AFFECTED AREAS. INSTEAD, IMMERSE
AFFECTED AREAS IMMEDIATELY IN ICE-COLD WATER UNTIL ALL HEAT HAS DISSIPATED. THEN WRAP THEM
IN GAUZE AND GET MEDICAL ATTENTION PROMPTLY.
INGESTION:
DO NOT GIVE ANYTHING BY MOUTH. DO NOT INDUCE VOMITING; PULMONARY COMPLICATIONS CAN RESULT.
CONSULT A PHYSICIAN OR POISON CONTROL CENTER AT ONCE.
SECTION 5 - FIRE HAZARDS AND THEIR MANAGEMENT
IGNITION DATA:
FLASH POINT: 180 DEGR. F, 82 DEGR. C
LOWER FLAMMABLE LIMIT: NOT DETERMINED
UPPER FLAMMABLE LIMIT: NOT DETERMINED
AUTOIGNITION TEMPERATURE: ABOVE 210 C / 410 F
COMBUSTION PRODUCTS: CAN INCLUDE OXIDES OF NITROGEN, CARBON, AND POSSIBLY SULFUR.
FIRE FIGHTING GUIDELINES:
EXTINGUISHING MEDIA: USE CLASS B EXTINGUISHANT, E.G., DRY CHEMICAL, FOAM, CARBON DIOXIDE,
OR WATER FOG. IN CLOSED TANKS, WATER OR FOAM MAY CAUSE FROTHING OR ERUPTION.
WEAR RESPIRATOR (PRESSURE DEMAND, SELF-CONTAINED BREATHING APPARATUS, MSHA/NIOSH-APPROVED)
AND FULL PROTECTIVE GEAR FOR WORKING FIRES. COOL EXPOSED CONTAINERS WITH WATER SPRAY.
M A T E R I A L S A F E T Y D A T A S H E E T
PITCH ROOF COATING PAGE: 3
======================== SECTION VI - ACCIDENTAL RELEASE MEASURES =======================
PERSONAL PROTECTION:
FOLLOW ALL PRECAUTIONS GIVEN IN SECTION 8, AND, IN ADDITION, WEAR PERMEATION-RESISTANT,
ELASTOMERIC BOOTS OR OVERSHOES.
CLEAN-UP:
ELIMINATE ALL SOURCES OF IGNITION AND, IF INDOORS, VENTILATE SPILL AREA. STOP SOURCE OF
SPILL OR LEAK IF POSSIBLE. CONTAIN SPILLAGE BY DIKING WITH SAND, EARTH, PIGS, OR OTHER
INERT MATERIAL IN ORDER TO PREVENT SPILLAGE FROM ENTERING SEWERS OR OPEN BODIES OF WATER
AND/OR TO PREVENT SOIL CONTAMINATION.
IN COMPLIANCE WITH 40 CFR PART 302, REPORT THE RELEASE IMMEDIATELY TO THE NATIONAL
RESPONSE CENTER IF AMOUNT RELEASED EXCEEDS 148 POUNDS, AN AMOUNT BASED UPON THE CONCENTRATION
OF BENZO[B]FLUORANTHENE (RQ - 1 LB.) PRESENT IN THIS MATERIAL AND LISTED IN TABLE 302.4.
ALLOW HOT MATERIAL TO COOL, THEN TRANSFER SPILLAGE TO LABELED RECOVERY CONTAINERS.
======================== SECTION VII - HANDLING AND STORAGE =======================
ELIMINATE IGNITION SOURCES. STORE IN TIGHTLY CLOSED, LABELED CONTAINERS PROTECTED FROM PHYSICAL
DAMAGE AND SEPARATED FROM OXIDIZERS. STORAGE LOCATIONS MUST MEET, AS A MINIMUM, ALL APPLICABLE
REQUIREMENTS OF ANSI/NFPA 30 - FLAMMABLE AND COMBUSTIBLE LIQUIDS CODE (1993) AS IT APPLIES TO
CLASS LILA LIQUIDS.
======================== SECTION VIII - PROTECTION FROM OVER EXPOSURE =======================
VENTILATION AND CONTAINMENT:
KEEP CONTAINERS CLOSED WHEN NOT IN USE. IF INDOORS, USE EITHER LOCAL OR GENERAL EXHAUST
VENTILATION SUFFICIENT TO KEEP VAPOR AND FUME LEVELS BELOW APPLICABLE EXPOSURE LIMITS. IF
OUTDOORS, STAY UPWIND WHENEVER PRACTICAL TO DO SO.
RESPIRATORY PROTECTION:
IF VENTILATION/CONTAINMENT MEASURES DO NOT RELIABLY PROTECT AGAINST INHALATION OVEREXPOSURE,
WEAR MSHA/NIOSH-APPROVED RESPIRATOR SUITABLE FOR PROTECTION FROM THE VAPOR CONCENTRATIONS
ENCOUNTERED.
EYE PROTECTION:
WEAR SPLASH GOGGLES (ANSI Z87.1A-1991) WHEN POURING OR TRANSFERRING THIS MATERIAL. DO NOT
WEAR CONTACT LENSES.
SKIN PROTECTION:
AVOID SKIN CONTACT BY WEARING PERMEATION-RESISTANT, ELASTOMERIC GLOVES AND CLOTHES WITH
LONG SLEEVES AND PANTS. REPLACE ELASTOMERIC PROTECTIVE EQUIPMENT WHENEVER IT BECOMES SWOLLEN,
GUMMY, TORN, OR SHOWS EVIDENCE OF BARRIER LOSS. APPLY A SOLVENT-RESISTANT SKIN BARRIER CREAM
TO AREAS OF SKIN THAT MAY COME INTO CONTACT WITH MATERIAL. IF WORKING OUT-OF-DOORS, FIRST
APPLY SUNSCREEN LOTION WITH A HIGH SUN BLOCK PROTECTION FACTOR TO SKIN EXPOSED TO SUNLIGHT,
THEN APPLY BARRIER CREAM.
OTHER PROTECTIVE MEASURES:
AN EYEWASH STATION AND EMERGENCY SHOWER (ANSI Z358.1-1990) SHOULD BE READILY AVAILABLE.
PERSONAL HYGIENE:
REMOVE PRODUCT FROM SKIN WITH VEGETABLE OIL WHENEVER OBSERVED; REAPPLY BARRIER CREAM AS
APPROPRIATE. WASH HANDS AND FOREARMS WITH SOAP AND WATER AFTER HANDLING, AND ESPECIALLY
BEFORE EATING OR SMOKING. SHOWER AT THE END OF EACH WORK SHIFT. LAUNDER CONTAMINATED CLOTHING
SEPARATE FROM OTHER LAUNDRY BEFORE REUSE.
======================== SECTION IX - PHYSICAL AND CHEMICAL DATA =======================
APPEARANCE: BLACK, SEMI-SOLID PASTE
SPECIFIC GRAVITY: 1.0-1.2
ODOR: PETROLEUM HYDROCARBON
PCT. VOLATILES: 25 (APPROX.)
WATER SOLUBILITY: NEGLIGIBLE I
NTITIAL BOILING PT.: 150 C / 302 F
VAPOR DENSITY: ABOVE 1.0
VAPOR PRESSURE: 2 MM HG @ 20 C (EST.)
M A T E R I A L S A F E T Y D A T A S H E E T
PITCH ROOF COATING PAGE: 4
======================== SECTION X - STABILITY AND REACTIVITY =======================
STABILITY:
THIS MATERIAL IS STABLE UNDER NORMAL CONDITIONS OF STORAGE AND HANDLING. THAT IS, IT
DOES NOT REACT WITH COMMON SUBSTANCES (AIR, WATER, ETC.), NOR POLYMERIZE, NOR DECOMPOSE
DURING FORESEEABLE CONDITIONS OF STORAGE OR USE.
REACTIVITY:
MATERIAL REACTS VIOLENTLY WITH STRONG OXIDIZERS SUCH AS LIQUID CHLORINE, SODIUM OR POTASSIUM
HYPOCHLORITE, NITRIC ACID AND PEROXIDES.
======================== SECTION XIII - DISPOSAL =======================
CONTAINERS:
EMPTY CONTAINERS MAY CONTAIN RESIDUES THAT COULD BURN OR CAUSE CONTAINER TO RUPTURE VIOLENTLY
IF HEATED OR IGNITED. OBSERVE ALL MSDS AND LABEL PRECAUTIONS UNTIL CONTAINERS ARE RECONDITIONED.
DO NOT WELD ON OR APPLY HEAT OR FLAME TO CONTAINER. PREVENT UNAUTHORIZED REUSE OF CONTAINERS.
FOLLOW ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS IN DISPOSING OF CONTAINERS.
WASTE DISPOSAL:
INCINERATE AT A PERMITTED FACILITY IN ACCORDANCE WITH LOCAL AND STATE REGULATIONS. IF FLASH
POINT OF WASTE LIQUID IS BELOW 140 F, STORE AND SHIP WASTE AS UNLISTED HAZARDOUS WASTES
CHARACTERISTIC OF LGNITABILITY, RCRA #D-001, RQ: 100 LBS. (PER 40 CFR PARTS 261 AND 262).
IF WASTE IS A SOLVENT-FREE DRY SOLID, IT IS NOT CLASSIFIED AS HAZARDOUS WASTE.
======================== SECTION XIV - TRANSPORTATION REGULATIONS =======================
THE FOLLOWING INFORMATION APPLIES TO GROUND SHIPMENTS WITHIN NORTH AMERICA, BUT MAY NOT APPLY
OTHERWISE.
PACKAGED SHIPMENTS - BILL OF LADING DESCRIPTIONS
UP TO 5 GAL:
NOT DOT-REGULATED
DRUMS:
RQ, COMBUSTIBLE LIQUID, NOS, NA1993, PG III
(PETROLEUM DISTILLATES, TAR PITCH/HAZ SUB: BENZO[A]PYRENE, BENZO[B]FLUORANTHENE)
BULK SHIPMENTS - BILL OF LADING DESCRIPTIONS
LOADING TEMPERATURE RANGE: BELOW 180 DEGR. F:
RQ COMBUSTIBLE LIQUID, NOS, NA1993, PG III
(PETROLEUM DISTILLATES, TAR PITCH/HAZ SUB: BENZO[A]PYRENE, BENZO[B]FLUORANTHENE)
LOADING TEMPERATURE RANGE: 180-211 DEGR. F:
RQ TARS, LIQUID, 3 (FLAMMABLE LIQUID), UN1999, PG III
(TAR PITCH/CONTAINS BENZO[B]FLUORANTHENE, BENZO[A]PYRENE)
LOADING TEMPERATURE RANGE: ABOVE 211 DEGR. F:
RQ, HOT, FLAMMABLE LIQUID, ELEVATED TEMPERATURE MATERIAL, NOS, 3, UN3256, PG III
(PETROLEUM DISTILLATES, TAR PITCH/HAZ SUB: BENZO[A]PYRENE, BENZO[B]FLUORANTHENE)
SECTION 15 - OTHER REGULATORY INFORMATION
ALL INGREDIENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY IN ACCORDANCE WITH SECTION 8(B).
THE FOLLOWING INGREDIENTS ARE REPORTABLE UNDER SARA SECTION 313 (40 CFR PART 372, SUBPART D):
NAME CAS NUMBER CONCENTRATION, WT. PCT
POLYCYCLIC AROMATIC COMPOUND CATEGORY NONE 1.7
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